Glossary of terms
- Aerosol
- A dispersion of a liquid or solid in a gas.
Acid esterification
- A common approach for removing free
fatty acids from the feedstock is via acid catalyzed esterification in the
presence of methanol. This converts the free fatty acids to methyl esters
(e.g., biodiesel). Acid esterification equipment requires the use of
stainless steel equipment due to the corrosive nature of the process.
- Anhydrous-
"Without water" - transesterification of biodiesel must be an
anhydrous process or funny things hapen. Water in the vegetable oil causes
either no reaction or cloudy biodiesel, and water in lye or methanol
renders it less useful or even useless, depending on how much water is
present. Either let your vegetable oil settle for 2-3 days before using
and drain the water off the bottom, or heat the oil and boil off the
water. Store lye and methanol in (separate) air-tight containers.
Biodiesel
- An environmentally safe, low polluting fuel for most diesel internal
combustion and turbine engines, containing methyl or ethyl esters made from
fresh or waste vegetable oils (triglycerides).
Biodiesel Recipe - Like a recipe for
making a cake, a biodiesel recipe specifies the ingredients required, and the
steps for combining and processing them to make biodiesel fuel. The most
common recipe uses waste vegetable oil (WVO), methanol (wood alcohol), and
sodium hydroxide (caustic soda) to produce biodiesel and glycerine. The most
common steps are: (1) cleaning/heating WVO, (2) titration of WVO sample, (3)
combining methanol and sodium hydroxide in exact amounts, (4) combining (3)
with (1) and mixing at 50c, (5) waiting for separation, (6) separating the
biodiesel from the wastes, (7) washing and drying the biodiesel, (8) disposing
of the wastes.
Bubble Wash - A method of final washing of
biodiesel through air agitiation. Biodiesel floats above a quantity of water.
Bubbles from an aquarium air pump and air stone are injected into the water
causing the bubbles to rise. At the water/biodiesel interface, the air bubbles
carry water up through the biodiesel by surface tension. Simple diffusion
causes water soluable impurities in the biodiesel to be extracted into the
water. As the bubble reaches the surface and breaks, the water is freed and
percolates back down through the biodiesel again.
Blending
vegetable oils with petro diesel -
A number of methods exist to blend vegetable oil with petro diesel and
create a low viscosity fuel oil with similar properties to diesel. One such
method results in a product called AGTANE
and this is the result of mixing recycled Yellow Grease with hydrogen in the
presence of steam, later blended with heavy diesel oil.
Canola - a trademarked hybrid of rape
initially bred in Canada. Rape Seed Oil was produced in the 19th century as a
source of a lubricant for steam engines, and the oil has a bitter taste due to
high levels of acids. Canola has been bred to reduce the amount of acid,
yielding a palatable oil. Canola = CANadian Oil Low Acid. (unverified)
Colloidal size
- .001 micron to 1 micron in any dimension. Dispersions where the particle
size is in this range are referred to as colloidal aerosols, colloidal
emulsions, colloidal foams, or colloidal suspensions.
Cetane Number -
Measure of fuel ignition characteristics. Like
the octane number used for gasoline, the higher the value, the better the fuel
performance. A higher cetane number correlates with improved combustion,
improved cold starting, reduced noise, white smoke, HC, CO and particulate
emissions particularly during early warm-up phase. The EPA uses this parameter
as a measure of aromatic content in fuel. Typical Cetane numbers around the
world are as follows: Europe: 43 - 57, average 50 U.S. lower, minimum 40,
average 43.
Cloud point
- The temperature
at which the first wax crystals appear and a standardized ASTM test protocol
is used to determine this temperature.
Colloid
- A stable system
of small particles dispersed in something else. A multi-phase system in which
one dimension of a dispersed phase is of colloidal size. Colloids are the
liquid and solid forms of aerosols, foams, emulsions, and suspensions within
the colloidal size class. Milk and smoke are both colloids. Colloidal size is
typically .001 micron to 1 micron in any dimension. Dispersions where the
particle size is in this range are referred to as colloidal aerosols,
colloidal emulsions, colloidal foams, or colloidal suspensions.
Dispersion
- A stable or unstable system of fine particles,
larger than colloidal size, evenly distributed in a medium.
Emulsification - to emulsify - to form an
emulsion...as in mixing oil and vinegar in a blender. voila: salad dressing.
Emulsion - a usually unstable dispersion
of two liquids which do not normally mix (they are immiscible). Emulsions can
be formed either by mechanical aggitation, or by chemical processes. Unstable
emulstions will separate over time or temperature, stable emulsions will not
separate.
Esters - a product of the reaction of
acids (usually organic) and alcohols. ch3cooch3 - methyl acetate is the
simplest ester. one of the oxygens has a double bond. you can replace the
'ch3' part on the right with more ch2 chunks, and you get other methyl esters,
including biodiesel's methyl stearate. many of the esters smell good.
Ethanol - ethyl alcohol - c2h5oh -
ch3-ch2-oh = the intoxicating stuff in beer, and a good solvent. "beer is
proof that god loves us and wants us to be happy" :: ben franklin.
Foam
- A dispersion of a gas in a liquid or solid.
Glycerine - A byproduct of biodiesel
production: ch2-oh--ch-oh--ch2-oh each of the "oh" sites is one of
the three places where an ester is broken off of the triglyeride molecule (veg.
oil).
Gum Number
- The measure of the tendency of a
fuel to form gums via oxidation.
Iodine #
- Standard natural oil assay to measure the degree of unsaturation (or
the number of double bonds present) in vegetable oils and fats.
Kerosene - A thin oil distilled from
petroleum or shale oil, used as a fuel for heating and cooking, in lamps, and
as a denaturant for alcohol, diesel or WVO.
KOH - Potassium Hydroxide. used to make
biodiesel from ethanol. a metallic base.
Lye - a quaint american term for NaOH -
Sodium Hydroxide
Methanol - methyl alcohol - ch3oh - the
stuff they burn in top fuel eliminator dragsters and toy airplane engines. a
good solvent and a component of gasahol. lethal if consumed. In biodiesel
production, methanol is used to make methoxide. Methanol absorbs water from
the air, so keep the container closed tightly, and purchase methanol which is
known to be dry (anhydrous) or is 99.9% pure. solvent or paint grade methanol
may not be anhydrous, and you will run the risk of making soap.
Methoxide - a.k.a. sodium methoxide a.k.a.
sodium methylate - (Ch3-O+ Na-) - an organic salt, in pure form a white powder
- In biodiesel production, "methoxide" is a product of mixing
methanol and sodium hydroxide, yielding a solution of sodium methoxide in
methanol, and a significant amount of heat. sodium methoxide in methanol is a
liquid that kills nerve cells before you can feel the pain. rinse with water,
seek medical attention immediately. also highly explosive. making sodium
methoxide is the most dangerous step you deal with when making biodiesel. for
this reason, you should carefully consider the safety of the design of your
equipment and workspace before using, and you should wear protective clothing
and a respirator when handling. you should also make only what you intend to
use immediately.
NaOH - Lye, Sodium Hydroxide, Caustic
Soda, a.k.a. Red Devil Drain Cleaner... a metallic base. strongly alkaline and
extremely corrosive. mixing with fluids usually causes heat, and can create
enough heat to ignite flammables (such as methanol), so add slowly. For
biodiesel, this is one of the main reactants. Make sure you are purchasing
"anhydrous sodium hydroxide." Anhydrous means it's dry, and water
turns biodiesel into soap. Store this product in an airtight container to
prevent NaOH from absorbing water and CO2 from the air. Store separately.
Optimal PH for Biodiesel - 7
(seven)...neutral, same as distilled water (and most tap water).
pH - (mirriam - webster) a measure of
acidity and alkalinity of a solution that is a number on a scale on which a
value of 7 represents neutrality and lower numbers indicate increasing acidity
and higher numbers increasing alkalinity and on which each unit of change
represents a tenfold change in acidity or alkalinity and that is the negative
logarithm of the effective hydrogen-ion concentration or hydrogen-ion activity
in gram equivalents per liter of the solution; also : the condition
represented by a pH number.
Pyrolysis - The Pyrolysis cracking
vegetable oil method uses heat and pressure to change the nature of vegetable
oil. The Pyrolysis refining process does produce reduced viscosity oil and an
acceptable diesel fuel replacement.
Pour point
- The temperature at which the fuel is no longer pumpable.
Rape -
Rape Seed - Rape Seed Oil - a.k.a. Cole seed. A member of the Mustard family.
Any of a number of crops grown for oil from the seeds. Canola is a member of
this family. Another early term for this oil is Colza. Makes good biodiesel.
Saponification - The reaction of an ester
with a metallic base and water. The making of soap. This happens sometimes
when you use too much lye in a biodiesel reaction... No worries - you can
re-react the resulting top layer of unreacted liquid, and if you wish you can
turn the semi-solid bottom layer into soap by adding more lye (make sure you
know how much to add...).
Soy - Soy Oil, a vegetable oil pressed
from soy beans.
Soy Diesel - a media term for biodiesel
which accentuates the renewable nature of biodiesel. Popular in soy producing
regions.
SVO - Straight Vegetable Oil - burns well
in many diesels, but does not start engine, and will coke in the injectors as
a hot engine cools. a separate tank of petro diesel or biodiesel is often used
during starting and stopping engine, and an electric valve allows transfer to
the SVO tank.
Titration - as applied to biodiesel,
titration is the act of determining the acidity of a sample of WVO by the
dropwise addition of a known base to the sample while testing with pH paper
for the desired neutral pH=7 reading. by knowing how much base neutralizes an
amount of WVO, we discern how much base to add to the entire batch.
Transesterfication - Process of creating
esters from vegetable oil (a triglyceride), and sodium methoxide. Products are
Glycerine, Methyl Stearate, Methyl Oleate, Methyl Linoleate. (assuming soy veg
oil)
Viscosity - the "thickness" or
"thinness" of a fluid. methanol is "thin", having a low
viscosity, while vegetatable oil is "thick" having a high viscosity.
(mirriam - webster) the ratio of the tangential frictional force per unit area
to the velocity gradient perpendicular to the direction of flow of a liquid.
WVO - Waste Vegetable Oil - WVO is the
usual starting product for the making of biodiesel.
|